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The ligation of glutamate and cysteine to form dipeptide ϒ-glutamylcysteine (ϒ-GC) is the first and also the rate-limiting step of GSH de novo synthesis, which is controlled by ATP-dependent ligase GCL, a heterodimer of a catalytic subunit (GCLC) and modifier subunit (GCLM)

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Circulation 133 , AMP59–AMP59 (2016)